Kamala Harris has said that she would be comfortable with a Republican in her Cabinet. If that should turn out to be a possibility, I would think that Liz Cheney would be an excellent candidate for either Secretary of Defense or Secretary of Sate. She certainly has the brains and horsepower to handle either of those jobs, and for the most part those responsibilities would not seem to be in any great conflict with her other political values.
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I've no idea what slot she might be thinking of but if it helps get the country moving out of the current 2-party malaise I'm all for it.